Named as National Peace Ambasssadors are popular Kapamilya and Kapuso artists, big personalities, and advocates who include:
- Anne Curtis
- Gerald Anderson
- Blackeyed Peas's Apl.de.Ap
- Megan Young
- Mikael Daez
- Ramon Bautista
- Noel Cabangon
- Ebe Dancel
- Datu Khomeini Bansuan
- Christian Bautista
- Karylle
- Sam Concepcion
- Gloc-9
- Arnold Galang
- JC Buendia
- Kiray
- Igi Boy
- Rovilson Fernandez
- Philippine Azkals
All peace envoys will be joined by no other than President Aquino in speaking "I choose peace. I want peace - I am for peace!" at the Malacanang Palace on Friday, September 14. Other campaigns to be launched by OPAPP include the "I Choose: Peace" youth football program, in partnership with the Philippine Football Federation (IFF), and the "Business Partners for Peace" campaign for companies (like McDo and 7-11) promoting the peace advocacy.