Here is an updated list of Philippine Cabinet Secretaries and the Departments they respectively head under the leadership of President Benigno "PNoy" Aquino Jr. Credits to Next Ping for compiling this list and granting permission to share it.
Office of the Vice President:
Jejomar Binay
Executive Office:
Paquito N. Ochoa, Jr.
Office of the Presidential Spokesperson:
Edwin Lacierda
Department of Foreign Affairs:
Albert F. del Rosario
Department of Finance:
Cesar Purisima
Department of Justice:
Leila M. de Lima
Department of the Interior and Local Government:
Mar Roxas
Department of Health:
Dr. Enrique T. Ona
Department of Agriculture:
Proceso J. Alcala
Department of Public Works and Highways:
Rogelio L. Singson
Department of Transportation and Communications:
Joseph Emilio Abaya
Department of Education:
Br. Armin A. Luistro FSC
Department of Social Welfare and Development:
Corazon Juliano-Soliman
Department of Labor and Employment:
Rosalinda D. Baldoz
Department of Budget and Management:
Florencio B. Abad
Department of National Defense:
Voltaire T. Gazmin
Department of Science and Technology:
Engr. Mario G. Montejo
Department of Agrarian Reform:
Virgilio R. de los Reyes
Department of Tourism:
Ramon R. Jimenez, Jr.
Department of Trade and Industry:
Gregory L. Domingo
Department of Environment and Natural Resources:
Ramon J. P. Paje
Department of Energy:
Carlos Jericho L. Petilla
Commission on Higher Education:
Patricia B. Licuanan
Other Offices with Cabinet-level Rank
Metropolitan Manila Development Authority:
Francis N. Tolentino
Mindanao Development Authority:
Luwalhati R. Antonino
National Commission on Muslim Filipinos:
Mehol K. Sadain
National Anti-Poverty Commission:
Jose Eliseo M. Rocamora
National Economic and Development Authority:
Arsenio M. Balisacan
National Security Council:
Cesar P. Garcia, Jr.
Office of the Cabinet Secretary:
Jose Rene D. Almendras
Office of the Chief Presidential Legal Counsel:
Eduardo V. De Mesa
Office of the Political Adviser:
Ronaldo M. Llamas
Office of the Presidential Adviser on the Peace Process:
Teresita Quintos-Deles
Office of the Solicitor General:
Francis H. Jardeleza
Presidential Communications Development and Strategic Planning Office:
Ramon A. Carandang
Presidential Communications Operations Office:
Herminio B. Coloma, Jr.
Presidential Legislative Liaison Office:
Manuel N. Mamba
Presidential Management Staff:
Julia Andrea R. Abad
Technical Education and Skills Development Authority:
Joel J. Villanueva